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Pentaplutoniumtruthenium

Pentaplutonium triruthenium is a binary inorganic compound of ruthenium and plutonium with the formula Ru 3 Pu 5 crystals.

Pentaplutoniumtruthenium
General
Systematic
name
Pentaplutoniumtruthenium
Traditional namesTriruthenium pentaplutonium
Chem. formulaRu 3 Pu 5
Rat formulaPu 5 Ru 3
Physical properties
conditioncrystals
Molar mass1523.21 g / mol
Density14.9 g / cm³
Thermal properties
T. decomp.1025 [1] ° C

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Ru+5Pu→800oCPu5Ru3{\ displaystyle {\ mathsf {3Ru + 5Pu \ {\ xrightarrow {800 ^ {o} C}} \ Pu_ {5} Ru_ {3}}}}  

Physical Properties

Pentaplutonium triruthenium forms tetragonal crystal crystals, space group P 4 / mcm , cell parameters a = 1.07685 nm, c = 0.57473 nm, Z = 4, pentavungsten trisilicide type structure W 5 Si 3 [2] [3] [4] (cell parameters a = 0.8092 nm, c = 1.0023 nm [1] are also reported.)

The compound is formed by a peritectic reaction at a temperature of 1025 ° C [1] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  2. ↑ The Chemistry of the Actinide and Transactinide Elements / Lester R. Morss, Norman M. Edelstein, J. Fuger. - Springer, 2010. - T. 2. - ISBN 978-94-007-0210-3 .
  3. ↑ DT Cromer, AC Larson, RB Roof. The structure of Pu 5 Ru 3 // Acta Cryst .. - 1975.- T. B31 , No. 6 . - S. 1756-1757 . - DOI : 10.1107 / S056774087500605X .
  4. ↑ AV Beznosikova, NT Chebotarev, AS Luk'yanov, AV Chernyi, EA Smirnova. Crystal structure of Pu 5 Ru 3 , Pu 5 Rh 3 , Pu 5 Os 3 , Pu 5 Ir 3 , Pu 5 Pt 3 // Soviet Atomic Energy. - 1974. - T. 37 , No. 2 . - S. 842-846 . - DOI : 10.1007 / BF01125637 .


Source - https://ru.wikipedia.org/w/index.php?title= Pentaplutonium triruthenium&oldid = 94873428


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