Rubidium fluoroplutonate (V) is an inorganic compound, a complex plutonium and rubidium fluoride with the formula Rb 2 PuF 7 , green crystals.
| Fluoroplutonate | |
|---|---|
| Are common | |
| Systematic name | Fluoroplutonate (V) rubidium |
| Traditional names | heptafluoroplutonate (V) dirubidium; plutonium (V) -dirubidium fluoride |
| Chem. formula | Rb 2 PuF 7 |
| Physical properties | |
| condition | green crystals |
| Molar mass | 547.92 g / mol |
| Density | 4.8 g / cm³ |
Content
Getting
- Passing fluorine through a heated mixture of rubidium fluoride and plutonium tetrafluoride :
Physical Properties
Rubidium fluoroplutonate (V) forms green crystals of monoclinic syngony , cell parameters a = 0.627 nm, b = 1.342 nm, c = 0.884 nm, β ≈ 90 °, Z = 4, structure type K 2 NbF 7 [1] .
Chemical Properties
- Reacts with water.
Notes
- ↑ Synthesis of Lanthanide and Actinide Compounds / G. Meyer, Lester R. Morss. - Kluwer Academic Publishers, 1991 .-- 366 p. - ISBN 0-7923-1018-7 .
Literature
- Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.
- Beckman I.N. Plutonium. Study guide . - M: Moscow State University. M.V. Lomonosova, 2010 .-- 165 p. Archived February 23, 2015. Archived February 23, 2015 on Wayback Machine
- RA Penneman, George D. Sturgeon, LB Asprey, FH Kruse. Fluoride Complexes of Pentavalent Plutonium // J. Am. Chem. Soc .. - 1965. - T. 87 , No. 24 . - S. 5803–5804 . - DOI : 10.1021 / ja00952a059 .