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Fluoride plutonium (IV) -rubidium

Plutonium (IV) fluoride - inorganic compound, double salt of rubidium , plutonium and hydrofluoric acid with the formula RbPuF 5 , light green crystals, does not dissolve in water.

Fluoride plutonium
Are common
Systematic
name
Fluoride plutonium (IV) -rubidium
Traditional namesFluoride plutonium-rubidium, rubidium pentafluoroplutonate
Chem. formulaRbPuF 5
Physical properties
conditionlight green crystals
Molar mass424.46 g / mol
Density5.88 g / cm³
Chemical properties
Water solubility0.003 g / 100 ml

Content

Getting

  • The reaction of excess rubidium fluoride and plutonium (IV) nitrate [1] :
Pu(NO3)four+fiveRbF→RbPuFfive↓+fourKNO3{\ displaystyle {\ mathsf {Pu (NO_ {3}) _ {4} + 5RbF \ {\ xrightarrow {}} \ RbPuF_ {5} \ downarrow + 4KNO_ {3}}}  

Physical Properties

The plutonium (IV) -rubidium fluoride forms light green crystals of the trigonal syngony , space group R 3 , cell parameters a = 1,520 nm, c = 1,059 nm, Z = 18.

Not soluble in water.

Notes

  1. ↑ JH Simons. Fluorine Chemistry . - Academic Press, 1964.

Literature

  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Milyukova, MS, Gusev, NI, Senturin, IG, et al. Analytical Chemistry of Plutonium. - M .: Science, 1965. - 457 p.


Source - https://ru.wikipedia.org/w/index.php?title=Fluoride_plutonium ( IVIV - rubidium&oldid = 80372515


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