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Heptaplatin trisilicide

Heptaplatinum trisilicide - a binary inorganic compound of platinum and silicon with the formula Pt 7 Si 3 , crystals, does not dissolve in water. The compound is also assigned the formula Pt 12 Si 5 .

Heptaplatin trisilicide
General
Systematic
name
Heptaplatin trisilicide
Traditional namesSiliceous platinum
Chem. formulaPt 7 Si 3
Physical properties
conditioncrystals
Molar mass1449.80 g / mol
Density16.8 g / cm³
Thermal properties
T. decomp.986 ° C
Classification
Reg. CAS number152064-08-9, 12066-95-4

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 notes
  • 4 Literature

Getting

  • Sintering of stoichiometric amounts of pure substances:
7Pt+3Si→986oCPt7Si3{\ displaystyle {\ mathsf {7Pt + 3Si \ {\ xrightarrow {986 ^ {o} C}} \ Pt_ {7} Si_ {3}}}}  

Physical Properties

Heptaplatin trisilicide forms tetragonal crystal crystals, space group I 4 / n , cell parameters a = 1.3404 nm, c = 0.5451 nm, Z = 8.

At a temperature of 280 ° C, a transition to the tetragonal syngony phase occurs, the cell parameters a = 1.3995 nm, c = 0.554 nm, Z = 8.

Not soluble in water.

Notes

Literature

  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .


Source - https://ru.wikipedia.org/w/index.php?title= Heptaplatinum trisilicide&oldid = 80371882


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