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Platinum molybdenum

Platinum molybdenum is a binary inorganic compound, platinum and molybdenum intermetallic compound with the formula MoPt, crystals.

Platinum molybdenum
Are common
Systematic
name
Platinum molybdenum
Traditional namesMolybdenum platinum
Chem. formulaPtmo
Rat formulaMopt
Physical properties
conditioncrystals
Molar mass291.02 g / mol
Density16.0 g / cm³
Thermal properties
T. decomp.1300 ° C
Enthalpy of Education-55 [1] kJ / mol
Classification
Reg. CAS number12033-27-1

Getting

  • Fusion of stoichiometric amounts of pure substances:
Pt+Mo→1300oCMoPt{\ displaystyle {\ mathsf {Pt + Mo \ {\ xrightarrow {1300 ^ {o} C}} \ MoPt}}}  

Physical Properties

Platinum molybdenum forms crystals of rhombic syngony , space group P mma , cell parameters a = 0.4462 nm, b = 0.2725 nm, c = 0.4951 nm, Z = 2, cadmium gold type structure AuCd [2] [3] [4 ] ] .

The compound is formed by a peritectoid reaction at 1300 ° C and has a wide homogeneity region of 43–53 at.% Platinum [2] .

Notes

  1. ↑ My.Y. Benarchid, N. David, J.-M. Fiorani, M. Vilasi, T. Benlaharche. [ https://www.researchgate.net/profile/My_Benarchid/publication/244385933 Enthalpies of formation of MoPt alloys by high temperature direct reaction synthesis calorimetry / links / 02e7e531deb6f84bbf000000.pdf Enthalpies of formation of Mo – Pt alloys high temperature synthesis calorimetry] // J. Chem. Thermodynamics. - 2009 .-- T. 41 . - S. 383–385 . - DOI : 10.1016 / j.jct.2008.10.006 .
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ B. Predel. Mo-Pt (Molybdenum-Platinum) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5H . - S. 1-2 . - DOI : 10.1007 / 10522884_2085 .
  4. ↑ Leo Brewer, RH Lamoreaux, R. Ferro, R. Marazza. The Mo-Pt system (Molybdenum-Platinum) // Bulletin of Alloy Phase Diagrams. - 1980. - T. 1 , No. 2 . - S. 89-92 . - DOI : 10.1007 / BF02881200 .


Source - https://ru.wikipedia.org/w/index.php?title=Platinamolybdenum &oldid = 88095951


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