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Diplatinalithium

Diplatinalithium is an intermetallic compound of platinum and lithium with the composition LiPt 2 .

Diplatinalithium
Are common
Systematic
name
Diplatinalithium
Chem. formulaPt 2 li
Rat formulaLipt 2
Physical properties
conditioncrystals
Molar mass397.10 g / mol
Density11.5 g / cm³
Thermal properties
T. decomp.> 1000 ° C

Getting

  • Fusion of stoichiometric amounts of pure substances [1] :
2Pt+Li→540oCLiPt2{\ displaystyle {\ mathsf {2Pt + Li \ {\ xrightarrow {540 ^ {o} C}} \ LiPt_ {2}}}} {\displaystyle {\mathsf {2Pt+Li\ {\xrightarrow {540^{o}C}}\ LiPt_{2}}}}

Physical Properties

It crystallizes in cubic syngony , the space group is F d 3 m , the cell parameters are a = 0.76932 nm, Z = 8, and the structure is of the type of dimmedium MgCu 2 ( Laves phase ) [2] [3] .

It has a homogeneity region of 66–73 at.% Platinum.

Notes

  1. ↑ JJ Zuckerman. Inorganic Reactions and Methods, The Formation of Bonds to Group-I, -II, and -IIIB Elements . - John Wiley & Sons, 2009 .-- 576 p. - ISBN 978-0-470-14549-4 .
  2. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ B. Predel. Li-Pt (Lithium-Platinum) // Landolt-Börnstein - Group IV Physical Chemistry. - 1997. - T. 5H . - S. 1-2 . - DOI : 10.1007 / 10522884_1917 .


Source - https://ru.wikipedia.org/w/index.php?title=Diplatinitalium &oldid = 79831559


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