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Triplatin pentagadolinium

Triplatin pentagadolinium is a binary inorganic compound of platinum and gadolinium with the formula Gd 5 Pt 3 , crystals.

Triplatin pentagadolinium
Are common
Systematic
name
Triplatin pentagadolinium
Traditional namesPentagadolinium triplatin
Chem. formulaPt 3 Gd 5
Rat formulaGd 5 Pt 3
Physical properties
conditioncrystals
Molar mass1371.48 g / mol
Density11.6 g / cm³
Thermal properties
T. decomp.≈1600 ° C
Classification
Reg. CAS number65767-58-0

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pt+fiveGd→1600oCGdfivePt3{\ displaystyle {\ mathsf {3Pt + 5Gd \ {\ xrightarrow {1600 ^ {o} C}} \ Gd_ {5} Pt_ {3}}}}  

Physical Properties

Triplatin pentagadolinium forms hexagonal crystals, space group P 6 3 / mcm , cell parameters a = 0.8479 nm, c = 0.6275 nm, Z = 2, pentamanganese trisilicide type structure Mn 5 Si 3 [1] [2] [3 ] ] [4] .

The compound is formed by a peritectic reaction at a temperature of ≈1600 ° C.

Notes

  1. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Gd-Pt (Gadolinium-Platinum) // Landolt-Börnstein - Group IV Physical Chemistry. - 1996. - T. 5f . - S. 1-4 . - DOI : 10.1007 / 10501684_1442 .
  3. ↑ B. Predel. Gd - Pt (Gadolinium - Platinum) // Landolt-Börnstein - Group IV Physical Chemistry. - 2013 .-- S. 124 . - DOI : 10.1007 / 978-3-642-24778-1_78 .
  4. ↑ J. Le Roy, J.-M. Moreau, D. Paccard, E. Parthé. Structures of the rare-earth-platinum compounds R 7 Pt 3 , R 2 Pt, R 5 Pt 3 and RPt // Acta Cryst .. - 1978. - T. B34 , No. 1 . - S. 9-13 . - DOI : 10.1107 / S0567740878002198 .



Source - https://ru.wikipedia.org/w/index.php?title=Triplatinpentagadolinium&oldid=80371586


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