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Triplatinachrome

Tripletinachrome - a binary inorganic compound of platinum and chromium with the formula Pt 3 Cr, crystals.

Triplatinachrome
Are common
Systematic
name
Triplatinachrome
Traditional namesChromtriplatin
Chem. formulaPt 3 Cr
Rat formulaCrPt 3
Physical properties
conditioncrystals
Molar mass637.23 g / mol
Density18.1 g / cm³
Thermal properties
T. decomp.≈1200 ° C
Enthalpy of Education-31 [1] kJ / mol
Classification
Reg. CAS number12526-98-6

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pt+Cr→1200oCCrPt3{\ displaystyle {\ mathsf {3Pt + Cr \ {\ xrightarrow {1200 ^ {o} C}} \ CrPt_ {3}}}}  

Physical Properties

Tripletinachrome forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.3879 nm, Z = 1, structure like tri - gold AuCu 3 [2] [3] [4] [5] [6] .

The compound melts congruently at a temperature of ≈1200 ° C and has a wide homogeneity range of 34–85 at.% Platinum [2] .

Notes

  1. ↑ Johannes Preußner, Sara Prins, Rainer Völkl, Zi-Kui Liu, Uwe Glatzel. Determination of phases in the system chromium – platinum (Cr – Pt) and thermodynamic calculations // Materials Science and Engineering A. - 2009. - T. A 510–511 . - S. 322–327 . Archived January 13, 2015.
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  3. ↑ P. Franke, D. Neuschütz. Cr-Pt // Landolt-Börnstein - Group IV Physical Chemistry. - 2004 .-- T. 19B2 . - S. 1-5 . - DOI : 10.1007 / 10757405_89 .
  4. ↑ H. Okamoto. Cr-Pt (Chromium-Platinum) // Journal of Phase Equilibria and Diffusion. - 2009. - T. 30 , No. 3 . - S. 295-296 . - DOI : 10.1007 / s11669-009-9507-0 .
  5. ↑ B. Predel. [Landolt-Börnstein - Group IV Physical Chemistry Cr-Pt (Chromium-Platinum)]. - 1994 .-- T. 5d . - S. 1-4 . - DOI : 10.1007 / 10086090_1003 .
  6. ↑ M. Venkatraman, JP Neumann. The Cr-Pt (Chromium-Platinum) system // Bulletin of Alloy Phase Diagrams. - 1990. - T. 11 , No. 1 . - S. 16-21 . - DOI : 10.1007 / BF02841579 .


Source - https://ru.wikipedia.org/w/index.php?title= Tripletinachrome&oldid = 92087495


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