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Tripalladium vanadium

Tripalladium vanadium is a binary inorganic compound of palladium and vanadium with the formula Pd 3 V, crystals.

Tripalladium vanadium
General
Systematic
name
Tripalladium vanadium
Traditional namesVanadium tripalladium
Chem. formulaPd 3 v
Rat formulaVPd 3
Physical properties
conditioncrystals
Molar mass370.20 g / mol
Density10.7 g / cm³
Thermal properties
T. decomp.815 ° C [1]
Classification
Reg. CAS number59817-81-1
Smiles

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pd+V→815oCPd3V{\ displaystyle {\ mathsf {3Pd + V \ {\ xrightarrow {815 ^ {o} C}} \ Pd_ {3} V}}}  

Physical Properties

Tripalladium vanadium forms tetragonal crystal crystals, space group I 4 / mmm , cell parameters a = 0.3847 nm, c = 0.7753 nm, Z = 2, structure type trialuminium titanium TiAl 3 [1] [2] [3] [4] .

The compound is formed as a result of ordering a solid solution congruently at a temperature of 815 ° C [1] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ B. Predel. Pd-V (Palladium-Vanadium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2458 .
  3. ↑ Peter Lamparter, Traudl Krabichler, Siegfried Steeb. Diffusionsuntersuchungen im System Palladium — Vanadium mit Hilfe der Mikrosonde // Z. Naturforsdi .. - 1972.- T. 27 a . - S. 960-965 .
  4. ↑ AE Dwight, JW Downey, RA Conner Jnr. Some AB 3 compounds of the transitiom metals // Acta Crystallographica. - 1961. - T. 14 , No. 1 . - S. 75–76 . - DOI : 10.1107 / S0365110X61000255 .



Source - https://ru.wikipedia.org/w/index.php?title= Tripalladium vanadium&oldid = 80371464


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