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Tetrapalladium triterbium

Tetrapalladium triterbium - binary inorganic compound of palladium and terbium with the formula Tb 3 Pd 4 , crystals.

Tetrapalladium triterbium
Are common
Systematic
name
Tetrapalladium triterbium
Traditional namesTriterium tetrapalladium
Chem. formulaPd 4 Tb 3
Rac formulaTb 3 pd 4
Physical properties
conditioncrystals
Molar mass902.46 g / mol
Density10.4 g / cm³
Thermal properties
T. melt.1370 ° C
Melting enthalpy-9.4 [1] kJ / mol
Classification
Reg. CAS number51200-37-4
SMILES

Getting

  • Fusion of stoichiometric amounts of pure substances:
fourPd+3Tb→1370oCTb3Pdfour{\ displaystyle {\ mathsf {4Pd + 3Tb \ {\ xrightarrow {1370 ^ {o} C}} \ Tb_ {3} Pd_ {4}}}}  

Physical Properties

Tetrapalladium triterbium forms crystals of the trigonal syngony , space group R 3 , cell parameters a = 1.3178 nm, c = 0.5708 nm, Z = 6, the structure of tetrapalladium tripleutonium type Pu 3 Pd 4 [2] [3] [4] .

The compound melts congruently at a temperature of 1370 ° С [2] .

Notes

  1. ↑ P. Franke, D. Neuschütz. Pd-Tb (Palladium - Terbium) // Landolt-Börnstein - Group IV Physical Chemistry. - 2007. - T. 19B5 . - p . 1-4 . - DOI : 10.1007 / 978-3-540-45280-5_101 .
  2. ↑ 1 2 State diagrams of double metallic systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ H. Okamoto. Pd-Tb (Palladium-Terbium) // Journal of Phase Equilibria. - 1991. - Vol. 12 , No. 2 . - p . 252-253 . - DOI : 10.1007 / BF02645730 .
  4. ↑ B. Predel. Pd-Tb (Palladium-Terbium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - V. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2450 .



Source - https://ru.wikipedia.org/w/index.php?title=Tetrapalladium triterbium&oldid = 80370837


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