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Palladium samary

Palladium samarium is a binary inorganic compound of palladium and samarium with the SmPd formula, crystals.

Palladium samary
Are common
Systematic
name
Palladium samary
Traditional namesSamarium palladium
Chem. formulaPdSm
Rac formulaSmpd
Physical properties
conditioncrystals
Molar mass256.78 g / mol
Density9.3 g / cm³
Thermal properties
T. melt.1270 ° C
Classification
Reg. CAS number39293-95-3
SMILES

Getting

  • Fusion of stoichiometric amounts of pure substances:
Pd+Sm→1270SmPd{\ displaystyle {\ mathsf {Pd + Sm \ {\ xrightarrow {1270}} \ SmPd}}}  

Physical Properties

Palladium samarium forms crystals of several modifications. The high-temperature modification is formed at temperatures above 960 ÷ 982 ° C and belongs to the rhombic syngony , the space group C mcm , cell parameters a = 0.377 nm, b = 1.065 nm, c = 0.456 nm, Z = 4, chromium boride CrB type structure [1 ] [2] [3] .

The compound melts congruently at a temperature of 1270 ° C and has a homogeneity range of 1 ÷ 1.5 at.% [1] .

Notes

  1. ↑ 1 2 State diagrams of double metallic systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ P. Franke, D. Neuschütz. Pd-Sm (Palladium - Samarium) // Landolt-Börnstein - Group IV Physical Chemistry. - 2007. - T. 19B5 . - p . 1-4 . - DOI : 10.1007 / 978-3-540-45280-5_100 .
  3. ↑ B. Predel. Pd-Sm (Palladium-Samarium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - V. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2446 .



Source - https://ru.wikipedia.org/w/index.php?title=Palladium samarium&oldid = 88750571


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