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Dipalladium hafnium

Dipalladium - hafnium - a binary inorganic compound, intermetallic palladium and hafnium with the formula HfPd 2 , crystals.

Dipalladium hafnium
General
Systematic
name
Dipalladium hafnium
Traditional namesHafnium dipalladium
Chem. formulaPd 2 hf
Rat formulaHfpd 2
Physical properties
conditioncrystals
Molar mass391.33 g / mol
Density12.9 g / cm³
Thermal properties
T. melt.2075 ° C [1]
Classification
Smiles

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Pd+Hf→2075oCHfPd2{\ displaystyle {\ mathsf {2Pd + Hf \ {\ xrightarrow {2075 ^ {o} C}} \ HfPd_ {2}}}}  

Physical Properties

Dipalladium gafnium forms tetragonal crystals, space group I 4 / mmm , cell parameters a = 0.3410 nm, c = 0.8635 nm, Z = 2, structure type MoSi 2 molybdenum disilicide [1] [2] .

The compound melts congruently at a temperature of 2075 ° C and is stable at temperatures above 1370 ° C [1] [3] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Hf-Pd (Hafnium-Palladium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1996. - T. 5f . - S. 1-2 . - DOI : 10.1007 / 10501684_1591 .
  3. ↑ SN Tripathi, SR Bharadwaj. The Hf-Pd (hafnium-palladium) system // Journal of Phase Equilibria. - 1995. - T. 16 , No. 6 . - S. 527-531 . - DOI : 10.1007 / BF02646725 .


Source - https://ru.wikipedia.org/w/index.php?title=Dipalladium hafnium&oldid = 80966940


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