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Tripalladium Gadolinium

Tripalladium - gadolinium is a binary inorganic compound of palladium and gadolinium with the formula GdPd 3 , crystals.

Tripalladium Gadolinium
Are common
Systematic
name
Tripalladium Gadolinium
Chem. formulaPd 3 gd
Rat formulaGdpd 3
Physical properties
conditioncrystals
Molar mass476.51 g / mol
Density11.7 g / cm³
Thermal properties
T. melt.1630 ° C [1]
Enthalpy of Education-80 [2] kJ / mol
Classification
Reg. CAS number12140-59-9

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pd+Gd→1630oCGdPd3{\ displaystyle {\ mathsf {3Pd + Gd \ {\ xrightarrow {1630 ^ {o} C}} \ GdPd_ {3}}}}  

Physical Properties

Tripalladium-gadolinium forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.40661 nm, Z = 1, structure like tri - gold AuCu 3 [1] [3] .

The compound melts congruently at a temperature of 1630 ° C; it has a homogeneity region with a width of ≈6 at.% [1] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Gd-Pd (Gadolinium-Palladium) // Landolt-Börnstein - Group IV Physical Chemistry 2013, pp. - 2013 .-- S. 120-123 . - DOI : 10.1007 / 978-3-642-24778-1_77 .
  3. ↑ B. Predel. Gd-Pd (Gadolinium-Palladium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1996. - T. 5f . - S. 1-3 . - DOI : 10.1007 / 10501684_1438 .



Source - https://ru.wikipedia.org/w/index.php?title= Tripalladium gadolinium&oldid = 88086997


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