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Tripalladium heptagadolinium

Tripalladium heptagadolinium is a binary inorganic compound of palladium and gadolinium with the formula Gd 7 Pd 3 , crystals.

Tripalladium heptagadolinium
Are common
Systematic
name
Tripalladium heptagadolinium
Traditional namesHeptagadolinium tripalladium
Chem. formulaPd 3 gd 7
Rat formulaGd 7 pd 3
Physical properties
conditioncrystals
Molar mass1420.01 g / mol
Density8.7 g / cm³
Thermal properties
T. decomp.812 ° C [1]
Classification
Reg. CAS number39417-19-1

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Pd+7Gd→812oCGd7Pd3{\ displaystyle {\ mathsf {3Pd + 7Gd \ {\ xrightarrow {812 ​​^ {o} C}} \ Gd_ {7} Pd_ {3}}}}  

Physical Properties

Tripalladium heptagadolinium forms crystals of hexagonal syngony , cell parameters a = 0.9980 nm, c = 0.6276 nm, Z = 1 [2] .

The compound is formed by a peritectic reaction at a temperature of 812 ° C [1] .

It has a high magnetocaloric effect [3] .

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ B. Predel. Gd-Pd (Gadolinium-Palladium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1996. - T. 5f . - S. 1-3 . - DOI : 10.1007 / 10501684_1438 .
  3. ↑ Canepa F., Napoletano M., Cirafici S., Merlo F. The magnetocaloric effect in Gd 7 Pd 3 and Gd 7 Pd 3-x Ni x compounds // Magnetics Conference, 2002. INTERMAG Europe 2002. Digest of Technical Papers. 2002 IEEE International. - 2002. - ISSN 0-7803-7365-0 . - DOI : 10.1109 / INTMAG.2002.1001083 .



Source - https://ru.wikipedia.org/w/index.php?title= Tripalladium heptagadolinium&oldid = 88086881


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