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Diosmitorium

Diosmitium is a binary inorganic compound, osmium and thorium intermetallic compound with the formula ThOs 2 , crystals.

Diosmitorium
Are common
Systematic
name
Diosmitorium
Traditional namesThorium diosmium
Chem. formulaOs 2 Th
Rat formulaThos 2
Physical properties
conditioncrystals
Molar mass612.50 g / mol
Density17.7 g / cm³
Thermal properties
T. melt.2480 [1]
Classification
Reg. CAS number12725-88-1

Getting

  • Fusion of stoichiometric amounts of pure substances:
2Os+Th→2480oCThOs2{\ displaystyle {\ mathsf {2 \, Os + Th \ {\ xrightarrow {2480 ^ {o} C}} \ ThOs_ {2}}}}  

Physical Properties

The diosmithium forms cubic syngonium crystals, the space group F d 3 m , the cell parameters a = 0.77050 nm, Z = 8, the structure of the type of dimethyl magnesium MgCu 2 ( Laves phase ) [2] [3] [4] [5] .

The compound melts congruently at a temperature of 2480 ° C [1] .

Notes

  1. ↑ 1 2 H. Kleykamp. Thermodynamische untersuchungen in den systemen Thorium-Osmium und Thorium-Iridium // Journal of the Less Common Metals. - 1979. - T. 63 , No. 1 . - S. P25 – P33 . - DOI : 10.1016 / 0022-5088 (79) 90218-2 .
  2. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  3. ↑ P. Chiotti, VV Akhachinskij, I. Ansara, MH Rand. The Os − Th (Osmium − Thorium) system // Bulletin of Alloy Phase Diagrams June, Volume, Issue, pp. - 1982. - T. 3 , No. 1 . - S. 101-102 . - DOI : 10.1007 / BF02873429 .
  4. ↑ B. Predel. Os-Th (Osmium-Thorium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998 .-- T. 5I . - S. 1-2 . - DOI : 10.1007 / 10542753_2356 .
  5. ↑ JR Thomson. Alloys of thorium with certain transition metals II. The systems thorium-osmium, thorium-iridium and thorium-platinum // Journal of the Less Common Metals. - 1964. - T. 6 , No. 1 . - S. 3–10 . - DOI : 10.1016 / 0022-5088 (64) 90003-7 .


Source - https://ru.wikipedia.org/w/index.php?title=Diosmithory&oldid=80966842


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Clever Geek | 2019