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Osmiigafny

Osmium - hafnium is a binary inorganic compound, osmium and hafnium intermetallic compound with the formula HfOs, crystals.

Osmiigafny
Are common
Systematic
name
Osmiigafny
Traditional namesHafnium osmium
Chem. formulaOshf
Rat formulaHfos
Physical properties
conditioncrystals
Molar mass368.72 g / mol
Density18.0 g / cm³
Thermal properties
T. melt.2595 [1] ° C
T. decomp.2520 [2] ° C
Enthalpy of Education-62 [3] kJ / mol
Classification
Reg. CAS number12358-86-0

Getting

  • Fusion of stoichiometric amounts of pure substances:
Os+Hf→2520oCHfOs{\ displaystyle {\ mathsf {Os + Hf \ {\ xrightarrow {2520 ^ {o} C}} \ HfOs}}}  

Physical Properties

Osmium-hafnium forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.3239 nm, Z = 1, structure type cesium chloride CsCl [2] .

The compound melts congruently at a temperature of 2595 [1] ° C or is formed by a peritectic reaction at a temperature of 2520 [2] ° C, has a homogeneity region of 45 ÷ 51 at.% Osmium.

Notes

  1. ↑ 1 2 H. Okamoto. Hf-Os (Hafnium-Osmium) // Journal of Phase Equilibria and Diffusion. - 2007. - T. 28 , No. 6 . - S. 593 . - ISSN 1547-7037 . - DOI : 10.1007 / s11669-007-9201-z .
  2. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  3. ↑ Djenane Nawel. Utilisation du Modele de Bande-d Pour l'Estimation des Enthalpies de Formation d'Alliages Binaires et Application a l'Etablissement de Diagrammes de Phases . - Université El Hadj Lakhdar Batna, Faculté de science, Département de Physique: Présenté pour obtenir le diplôme de Magister en Physique, 2009.


Source - https://ru.wikipedia.org/w/index.php?title= Osmiigafny&oldid = 80967816


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