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Tristannide Yttrium

Yttrium tristannide is a binary intermetallic inorganic compound of yttrium and tin with the formula YSn 3 , crystals.

Tristannide Yttrium
Are common
Systematic
name
Tristannide Yttrium
Chem. formulaYsn 3
Physical properties
conditioncrystals
Molar mass445.04 g / mol
Density7.2 g / cm³
Thermal properties
T. decomp.515 ° C
Enthalpy of Education-50 [1] kJ / mol
Classification
Reg. CAS number12326-43-1
Smiles

Content

Getting

  • Fusion of stoichiometric amounts of pure substances:
Y+3Sn→515oCYSn3{\ displaystyle {\ mathsf {Y + 3Sn \ {\ xrightarrow {515 ^ {o} C}} \ YSn_ {3}}}}  

Physical Properties

Yttrium tristannide forms crystals of cubic syngony , space group P m 3 m , cell parameters a = 0.4666 nm, Z = 1, structure like tri - gold AuCu 3 [2] [3] .

The compound is formed by a peritectic reaction at a temperature of 515 ° C [2] .

At a temperature of 7 K, it transforms into a superconducting state [4] .

Notes

  1. ↑ G. Borzone, A. Borsese, R. Ferro. A Contribution to the Study of the Alloying Behavior of the Rare Earths with Tin // Zeitschrift für anorganische und allgemeine Chemie. - 1983. - T. 501 , No. 6 . - S. 199–208 . - DOI : 10.1002 / zaac.19835010624 .
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .
  3. ↑ B. Predel. Sn-Y (Tin-Yttrium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1998. - T. 5 J. - S. 1-2 . - DOI : 10.1007 / 10551312_2772 .
  4. ↑ K. Kawashima, M. Maruyama, M. Fukuma, J. Akimitsu. Superconducting state in YSn 3 with a AuCu 3 -type structure // Physical Review B. - 2010 .-- T. 82 . - S. 094517 . - DOI : 10.1103 / PhysRevB.82.094517 .

Literature

  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .


Source - https://ru.wikipedia.org/w/index.php?title=Tristannid_Yttria&oldid=92955435


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