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Tin antimonide

Tin antimonide is a binary inorganic compound of tin and antimony with the formula SbSn, crystals.

Tin antimonide
Are common
Systematic
name
Tin antimonide
Traditional namesAntimony tin
Chem. formulaSbsn
Physical properties
conditioncrystals
Molar mass240.47 g / mol
Density6.8 g / cm³
Thermal properties
T. decomp.425 ° C
Classification
Reg. CAS number28980-49-6
Reg. EINECS number

Content

Getting

  • Fusion of stoichiometric amounts of pure substances:
Sn+Sb→425oCSbSn{\ displaystyle {\ mathsf {Sn + Sb \ {\ xrightarrow {425 ^ {o} C}} \ SbSn}}}  

Physical Properties

Tin antimonide has a very large homogeneity region of 43–60.5 at.% (Β-phase) and, depending on its composition, forms crystals of several modifications:

  • stoichiometric composition of SbSn — cubic syngony , space group F m 3 m , cell parameters a = 0.6142 nm, Z = 4;
  • with deviation from the stoichiometric composition, trigonal syngony (quasicubic), cell parameters a = 0.6129 ÷ 0.6150 nm, α = 89.18 ÷ 89.7 °, Z = 4 [1] .

Notes

  1. ↑ CA MacKay. A method for determination of the rhombohedral angle of SbSn // Journal of Applied Crystallography. - 1969. - T. 2 , No. 6 . - S. 295-297 . - DOI : 10.1107 / S0021889869007230 .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2000. - T. 3 Book 2. - 448 p. - ISBN 5-217-02932-3 .


Source - https://ru.wikipedia.org/w/index.php?title=Antimonid_tova&oldid=91569244


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