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DISTANNID OF TRIGELESA

Trigeland distannide is a binary intermetallic inorganic compound of iron and tin with the formula Fe 3 Sn 2 , crystals.

DISTANNID OF TRIGELESA
General
Systematic
name
DISTANNID OF TRIGELESA
Chem. formulaFe 3 Sn 2
Rat formulaSn 2 Fe 3
Physical properties
conditioncrystals
Molar mass404.96 g / mol
Density8.3 g / cm³
Thermal properties
T. decomp.806 ° C
Enthalpy of Education-5.1 [1] kJ / mol
Classification
Reg. CAS number12023-56-2

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 notes
  • 4 Literature

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Fe+2Sn→806oCFe3Sn2{\ displaystyle {\ mathsf {3Fe + 2Sn \ {\ xrightarrow {806 ^ {o} C}} \ Fe_ {3} Sn_ {2}}}}  

Physical Properties

Trigeland distannide forms monoclinic syngony crystals, cell parameters a = 1.353 nm, b = 0.534 nm, c = 0.920 nm, β = 103 °, Z = 8 [2] [3] .

Connection by peritectic reaction at a temperature of 806 ° С [2] (807 ° С [1] , 815 ° С [4] ). At temperatures below 607 ° C, the compound is in a metastable state.

Notes

  1. ↑ 1 2 P. Franke, D. Neuschütz. Fe-Sn // Landolt-Börnstein - Group IV Physical Chemistry. - 2005 .-- T. 19B3 . - S. 1-4 . - DOI : 10.1007 / 10757413_44 .
  2. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  3. ↑ B. Predel. Fe-Sn (Iron-Tin) // Landolt-Börnstein - Group IV Physical Chemistry. - 1995 .-- T. 5e . - S. 1-5 . - DOI : 10.1007 / 10474837_1342 .
  4. ↑ Ortrud Kubaschewski von Goldbeck. [IRON — Binary Phase Diagrams Iron — Tin Fe — Sn] (1982). - S. 139-142 . - DOI : 10.1007 / 978-3-662-08024-5_64 .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.



Source - https://ru.wikipedia.org/w/index.php?title= Trigeliza distannid&oldid = 80364605


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