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Dimethylaminotrimethylstannan

Dimethylaminotrimethylstannane is an organotin compound, the amino and methyl derivative of stannane with the formula Sn (CH 3 ) 3 N (CH 3 ) 2 , a colorless liquid, reacts with water.

Dimethylaminotrimethylstannan
General
Systematic
name
Dimethylaminotrimethylstannan
Traditional namesDimethylaminotrimethyltin
Chem. formulaSn (CH 3 ) 3 N (CH 3 ) 2
Physical properties
conditioncolorless liquid
Molar mass207.89 g / mol
Density1.22 g / cm³
Thermal properties
T. melt.1 ° C
T. bale.126 ° C
Classification
Reg. CAS number993-50-0
Reg. EINECS number213-610-9

Getting

  • The reaction of trimethyltin chloride and lithium dimethylamide :
2Sn(CH3)3Cl+(CH3)2NLi→Sn(CH3)3N(CH3)2+LiCl{\ displaystyle {\ mathsf {2Sn (CH_ {3}) _ {3} Cl + (CH_ {3}) _ {2} NLi \ {\ xrightarrow {}} \ Sn (CH_ {3}) _ {3} N (CH_ {3}) _ {2} + LiCl}}} {\displaystyle {\mathsf {2Sn(CH_{3})_{3}Cl+(CH_{3})_{2}NLi\ {\xrightarrow {}}\ Sn(CH_{3})_{3}N(CH_{3})_{2}+LiCl}}}

Physical Properties

Dimethylaminotrimethylstannan forms a colorless liquid.

Reacts with water.

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1992. - T. 3. - 639 p. - ISBN 5-82270-039-8 .
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  • Kocheshkov K.A., Zemlyansky N.N., Sheverdina N.I., Panov E.M. Organoelemental chemistry methods. Germanium, tin, lead. / ed. Nesmeyanov A.N., Kocheshkov K.A .. - M: Nauka, 1968. - 704 p.


Source - https://ru.wikipedia.org/w/index.php?title=Dimethylaminotrimethylstannan&oldid=100317698


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