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Pentaniobium tetraantimonide

Pentaniobium tetraantimonide is a binary inorganic compound of niobium and antimony with the formula Nb 5 Sb 4 , crystals.

Pentaniobium tetraantimonide
Are common
Systematic
name
Pentaniobium tetraantimonide
Traditional namesAntimony niobium
Chem. formulaNb 5 Sb 4
Physical properties
conditioncrystals
Molar mass951.57 g / mol
Density8.17 g / cm³
Thermal properties
T. decomp.950 ° C
Classification
Reg. CAS number12035-09-5

Content

Getting

  • Fusion of pure substances in an inert atmosphere:
fiveNb+fourSb→950oCNbfiveSbfour{\ displaystyle {\ mathsf {5Nb + 4Sb \ {\ xrightarrow {950 ^ {o} C}} \ Nb_ {5} Sb_ {4}}}}  

Physical Properties

Pentaniobium tetraantimonide forms tetragonal syngony crystals, space group I 4m , cell parameters a = 1.0314 nm, c = 0.35566 nm, Z = 2 [1] [2] .

At a temperature of 1.15 ÷ 4.2 K it goes into a superconducting state [3]

Notes

  1. ↑ Furuseth Sigrid, Kjekshus Arne. On the Arsenides and Antimonides of Niobium // Acta Chemica Scandinavica. - 1964 .-- T. 18 . - S. 1180-1195 . - DOI : 10.3891 / acta.chem.scand . 18-1180 .
  2. ↑ H. Boller, H. Nowotny. Kristallchemische Untersuchungen in Systemen (Ti, Nb, Ta, Mo, W) - (As, Sb) // Monatshefte für Chemie und verwandte Teile anderer Wissenschaften. - 1964. - T. 95 , No. 4-5 . - S. 1272-1282 . - DOI : 10.1007 / BF00904725 .
  3. ↑ Superconductors

Literature

  • Chemical Encyclopedia / Redkol .: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1992. - T. 3. - 639 p. - ISBN 5-82270-039-8 .
  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .


Source - https://ru.wikipedia.org/w/index.php?title=Pentaniobium tetraantimonide&oldid = 96502138


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