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Diberillium niobium

Diberillium niobium is a binary inorganic compound, an intermetallic niobium and beryllium with the formula NbBe 2 , crystals.

Diberillium niobium
Are common
Systematic
name
Diberillium niobium
Traditional namesDiberyllide niobium
Chem. formulaNbbe 2
Rat formulaBe 2 nb
Physical properties
conditioncrystals
Molar mass110.93 g / mol
Density5.28 g / cmΒ³
Thermal properties
T. decomp.1630 [1]
Classification
Reg. CAS number12009-98-2

Content

Getting

  • Sintering of stoichiometric amounts of pure substances:
Nb+2Beβ†’1350-1500oCNbBe2{\ displaystyle {\ mathsf {Nb + 2Be \ {\ xrightarrow {1350-1500 ^ {o} C}} \ NbBe_ {2}}}}  

Physical Properties

Diberillium niobium forms gray crystals of cubic syngony , the space group is F d 3 m , the cell parameters are a = 0.6535 nm, Z = 8, and the structure is of the type dimenmium magnesium MgCu 2 [2] .

The compound is formed by a peritectic reaction at 1630 Β° C [1] .

At a temperature of 2.15 K, it transforms into a superconducting state [3] .

Chemical Properties

  • Decomposes on heating:
3NbBe2β†’>1630oC2NbBe3+Nb{\ displaystyle {\ mathsf {3NbBe_ {2} \ {\ xrightarrow {> 1630 ^ {o} C}} \ 2NbBe_ {3} + Nb}}}  

Notes

  1. ↑ 1 2 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  2. ↑ DE Sands, A. Zalkin, OH Krikorian. The crystal structure of NbBe 2 and NbBe 3 // Acta Crystallographica. - 1959. - T. 12 , No. 6 . - S. 461-464 . - DOI : 10.1107 / S0365110X59001384 .
  3. ↑ Superconductors


Source - https://ru.wikipedia.org/w/index.php?title=Diberyllium niobium&oldid = 97268862


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Clever Geek | 2019