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Pentaniobium triphosphide

Pentaniobium triphosphide is an inorganic compound of niobium metal and phosphorus with the formula Nb 5 P 3 , dark gray crystals, insoluble in water.

Pentaniobium triphosphide
Are common
Systematic
name
Pentaniobium triphosphide
Traditional namesPhosphorous Niobium
Chem. formulaNb 5 P 3
Physical properties
conditiondark gray crystals
Molar mass557.45 g / mol
Density7.4 g / cm³

Content

Getting

  • Sintering of powdered niobium and red phosphorus:
fiveNb+3P→750oCNbfiveP3{\ displaystyle {\ mathsf {5Nb + 3P \ {\ xrightarrow {750 ^ {o} C}} \ Nb_ {5} P_ {3}}}}  

Physical Properties

Pentaniobium triphosphide forms dark gray crystals of rhombic syngony with the spatial group P nma , cell parameters a = 2.5384 nm, b = 0.3433 nm, c = 1.1438 nm, Z = 8 [1] [2] .

Not soluble in water.

Notes

  1. ↑ Eivind Hassler. The Crystal Structure of Nb 5 P 3 // Acta Chemica Scandinavica. - 1971. - T. 25 . - S. l29-140 .
  2. ↑ Ya. F. Lomnits'ka, AI Shupars'ka. Reactions of niobium and tungsten with phosphorus // Powder Metallurgy and Metal Ceramics. - 2006. - T. 45 , No. 7-8 . - S. 361-364 . - DOI : 10.1007 / s11106-006-0090-1 .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - Moscow : Mir, 1985 .-- V. 5 .-- 360 p.


Source - https://ru.wikipedia.org/w/index.php?title= Pentaniobium triphosphide&oldid = 80372079


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