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Triniobium Octabromide

Triniobium octabromide is an inorganic compound, a salt of niobium metal and hydrobromic acid with the formula Nb 3 Br 8 , black crystals, insoluble in water, acids and alkalis.

Triniobium Octabromide
Are common
Systematic
name
Triniobium Octabromide
Traditional namesNiobium bromide
Chem. formulaNb 3 Br 8
Physical properties
conditionblack crystals
Molar mass917.95 g / mol
Density5,4 g / cm³
Classification
Reg. CAS number12049-24-0

Content

Getting

  • The effect of bromine on niobium in a temperature gradient :
3Nb+fourBr2→760-800oCNb3Breight{\ displaystyle {\ mathsf {3Nb + 4Br_ {2} \ {\ xrightarrow {760-800 ^ {o} C}} \ Nb_ {3} Br_ {8}}}}  

Physical Properties

Triniobium octabromide forms black crystals of several modifications:

  • α-Nb 3 Br 8
  • β-Nb 3 Br 8 , trigonal syngony , space group R 3 m , cell parameters a = 0.70787 nm, c = 3.8957 nm, Z = 6 [1] .

α-Nb 3 Br 8 has a large region of homogeneity.

In the Nb 3 Br 8 molecule, niobium atoms form triangles; the Nb-Nb bond length is 0.288 nm.

It is not soluble in water, acids and alkalis.

Notes

  1. ↑ Katja Habermehl and Gerd Meyer. Triniobiumoctabromide, Nb 3 Br 8 , Revisited // Z. Naturforsch .. - 2010 .-- T. 65b . - S. 770–772 .

Literature

  • Manual on inorganic synthesis: B 6 tons / Ed. Brower G. .. - M .: Mir, 1985. - V. 5. - 360 p.


Source - https://ru.wikipedia.org/w/index.php?title= Triniobium octabromide&oldid = 80367799


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