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Pentanikeluran

Pentanikeluran - binary inorganic compound of nickel and uranium with the formula UNi 5 , crystals.

Pentanikeluran
Are common
Systematic
name
Pentanikeluran
Traditional namesUranpentanickel
Chem. formulaUNi 5
Rac formulaNi 5 U
Physical properties
conditioncrystals
Molar mass531.50 g / mol
Density11.2 g / cm³
Thermal properties
T. melt.1305 [1] ° C
Classification
Reg. CAS number12142-98-2

Getting

  • Fusion of stoichiometric amounts of pure substances:
fiveNi+U→1305oCUNifive{\ displaystyle {\ mathsf {5Ni + U \ {\ xrightarrow {1305 ^ {o} C}} \ UNi_ {5}}}}  

Physical Properties

Pentanickel uranium forms crystals of cubic system , space group F 4 3m , cell parameters a = 0.67958 nm, Z = 4, structure of pentaberillium gold type AuBe 5 [1] [2] [3] .

The compound melts congruently at a temperature of 1305 ° C. Has a homogeneity area of ​​82.5 ÷ 83.3 at. % nickel [1] [4] .

Notes

  1. ↑ 1 2 3 Diagrams of state of binary metallic systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  2. ↑ Chemist Handbook / Redcol .: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  3. Ric Perricone A., Noel H. 6 Ni, UNi 5 , UNi 2 , H. Crystal structure, and Ni, 0.3 Si 0.3, // Chemistry of Metals and Alloys. - 2008. - V. 1 , № 1 . - pp . 54-57 . (inaccessible link)
  4. ↑ DE Peterson. The Ni − U (Nickel-Uranium) system // Bulletin of Alloy Phase Diagrams. - 1988. - V. 9 , № 4 . - p . 490-493 . - DOI : 10.1007 / BF02881874 .


Source - https://ru.wikipedia.org/w/index.php?title=Pentanikeluran&oldid=96072962


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