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Stannid Trinickel

Trinickel stannide is a binary intermetallic inorganic compound of nickel and tin with the formula Ni 3 Sn, crystals.

Stannid Trinickel
Are common
Systematic
name
Stannid Trinickel
Chem. formulaNi 3 Sn
Rat formulaSnni 3
Physical properties
conditioncrystals
Molar mass294.79 g / mol
Density9.4 g / cm³
Thermal properties
T. melt.1174 ° C
Classification
Reg. CAS number12059-23-3
Reg. EINECS number

Content

Getting

  • The nysnite mineral Ni 3 Sn is found in nature [1] .
  • Fusion of stoichiometric amounts of pure substances:
3Ni+Sn→1174oCNi3Sn{\ displaystyle {\ mathsf {3Ni + Sn \ {\ xrightarrow {1174 ^ {o} C}} \ Ni_ {3} Sn}}}  

Physical Properties

Stannide trinickel forms crystals of two modifications [2] :

  • hexagonal syngony , space group P 6 3 / mmc , cell parameters a = 0.5295 nm, c = 0.4254 nm, Z = 2, cadmium trimagnesium type structure CdMg 3 , exists at a temperature below 977 ° C;
  • hexagonal syngony , cell parameters a = 0.263 nm, c = 0.422 nm, Z = 1, exists at temperatures above 977 ° C;

The compound melts congruently at a temperature of 1174 ° C [3] .

Notes

  1. ↑ Ralph Rowe, Joel D. Grice, Glenn Poirier, Chris J. Stanley? László Horváth. Nisnite, Ni3Sn, A New Nickel Mineral Species from the Jeffrey Mine, Asbestos, Quebec // The Canadian Mineralogist. - T. 49 , No. 2 . - S. 651-656 . - DOI : 10.3749 / canmin.49.2.651 .
  2. ↑ B. Predel. Ni-Sn (Nickel-Tin) // Landolt-Börnstein - Group IV Physical Chemistry / Ed. by O. Madelung. - 1998 .-- T. 5I. - Stb. 1-4 - ISBN 978-3-540-61712-9 .
  3. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.



Source - https://ru.wikipedia.org/w/index.php?title=Stannid_trinickel&oldid=88086893


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