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Aluminum tin

Aluminumnitrile - binary inorganic compound of nickel and aluminum with the formula AlNi 3 , crystals.

Aluminum tin
Are common
Systematic
name
Aluminum tin
Traditional namesTrinickel Aluminide
Chem. formulaAlNi 3
Rac formulaNi 3 Al
Physical properties
conditioncrystals
Molar mass203.06 g / mol
Density7.2 g / cm³
Thermal properties
T. melt.1395 ° C
Education enthalpy-168 [1] [2] kJ / mol
Classification
Reg. CAS number12003-81-5

Content

Getting

  • Fusion of stoichiometric amounts of pure substances:
3Ni+Al→1395oCAlNi3{\ displaystyle {\ mathsf {3Ni + Al \ {\ xrightarrow {1395 ^ {o} C}} \ AlNi_ {3}}}}  

Physical Properties

The aluminum-tin nickel forms crystals of the cubic system , the space group is P m3m , the cell parameters are a = 0.3589 nm, Z = 1, and the structure is AuCu 3 [3] .

The compound is formed by the peritectic reaction [4] at a temperature of 1395 ° C.

It has a homogeneity range of 73 ÷ 75 at.% Nickel.

Chemical Properties

  • Decomposes when heated:
AlNi3→>1395oCAlNi+2Ni{\ displaystyle {\ mathsf {AlNi_ {3} \ {\ xrightarrow {> 1395 ^ {o} C}} \ AlNi + 2Ni}}}  

Notes

  1. ↑ Albert I. Begunov, Mikhail P. Kuz'min. Thermodynamic Stability of Intermetallic Compounds in Technical Aluminum // Journal of Siberian Federal University. Engineering & Technologies. - 2014. - Vol. 2 , No. 7 . - pp . 132-137 .
  2. ↑ K. Rzyman, J.-C. Gachon. Formation Enthalpy of AlNi 3- Based Alloys with Calorimetric Solution and Direct Reaction Methods // Archives of Metallurgy and Materials. - 2010. - Vol. 55 , No. 4 . - p . 1021-1028 . - DOI : 10.2478 / v10172-010-0004-6 .
  3. ↑ Chemist Handbook / Redcol .: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  4. ↑ State Diagrams of Double Metallic Systems / Ed. N. P. Lyakishev. - M .: Mashinostroenie, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .


Source - https://ru.wikipedia.org/w/index.php?title=Aluminiumtrickel&oldid=94677366


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