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Dialium Neptunium

Dialuminium neptunium is a binary inorganic compound of neptunium and aluminum with the formula Al 2 Np, crystals.

Dialium Neptunium
Are common
Systematic
name
Dialium Neptunium
Traditional namesNeptunium Dialyuminides
Chem. formulaAl 2 Np
Rat formulaNpal 2
Physical properties
conditioncrystals
Molar mass290.96 g / mol
Density8.1 g / cm³
Thermal properties
T. melt.1590 ° C
Enthalpy of Education-110 [1] kJ / mol
Classification
Reg. CAS number12296-93-4

Getting

  • Fusion of stoichiometric amounts of pure substances:
Np+2Al→1590oCAl2Np{\ displaystyle {\ mathsf {Np + 2Al \ {\ xrightarrow {1590 ^ {o} C}} \ Al_ {2} Np}}}  

Physical Properties

Dialuminium neptunium forms crystals of cubic syngony , space group F d3m , cell parameters a = 0.7785 nm, Z = 8, structure like magnesium-copper Cu 2 Mg [2] .

The compound melts congruently at 1590 ° C [3] .

At a temperature of 56 K, a ferromagnetic transition occurs in the crystal [4] .

Notes

  1. ↑ D. Sedmidubský, RJM Konings, P. Souček. Ab-initio calculations and phase diagram assessments of An – Al systems (An = U, Np, Pu) // Journal of Nuclear Materials. - 2010. - T. 397 , No. 1-3 . - S. 1–7 . - DOI : 10.1016 / j.jnucmat.2009.11.0.023 .
  2. ↑ State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Mechanical Engineering, 1996. - T. 1. - 992 p. - ISBN 5-217-02688-X .
  3. ↑ H. Okamoto. Al-Pu (Aluminum-Plutonium) // Journal of Phase Equilibria and Diffusion. - 2012. - T. 33 , No. 6 . - S. 488 . - DOI : 10.1007 / s11669-012-0088-y .
  4. ↑ K. Aggarwal, L. Asch, S. Fredo, J. Gal, FN Gygax, B. Hitti, GM Kalvius, A. Kratzer, FJ Litterst, KH Münch. μSR on NpAl 2 // Hyperfine Interactions. - 1991. - T. 64 , No. 1-4 . - S. 401-404 . - DOI : 10.1007 / BF02396169 .



Source - https://ru.wikipedia.org/w/index.php?title=Dialuminium Neptunium&oldid = 80966280


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