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Hexamed Neodymium

Hexamed neodymium - a binary inorganic compound of neodymium and copper with the formula Cu 6 Nd, crystals.

Hexamed Neodymium
Are common
Systematic
name
Hexamed Neodymium
Traditional namesNeodymium Hexamide
Chem. formulaCu 6 Nd
Rat formulaNdcu 6
Physical properties
conditioncrystals
Molar mass525.52 g / mol
Density8.43 g / cm³
Thermal properties
T. melt.910 [1] ; 920 [2] ° C
Enthalpy of Education-11 [3] kJ / mol
Classification
Reg. CAS number12507-15-2

Getting

  • Fusion of stoichiometric amounts of pure substances:
Nd+6Cu→910oCCu6Nd{\ displaystyle {\ mathsf {Nd + 6Cu \ {\ xrightarrow {910 ^ {o} C}} \ Cu_ {6} Nd}}}  

Physical Properties

Hexamene neodymium forms rhombic syngony crystals, space group P mma , cell parameters a = 0.8064 nm, b = 0.5058 nm, c = 1.0113 nm, Z = 4, structure like CeCu 6 hexamer cerium [1] [3] .

The compound melts congruently at a temperature of 910 ° C [1] .

At a temperature of 6.1 K, an antiferromagnetic transition occurs in the compound [4] .

Notes

  1. ↑ 1 2 3 State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Metallurgy, 1997 .-- T. 2 .-- 1024 p. - ISBN 5-217-01569-1 .
  2. ↑ MM Carnasciali, GA Costa, EA Franceschi. Phase equilibria in the Nd-Cu system // Journal of the Less Common Metals. - 1983. - T. 92 , No. 1 . - S. 97–103 . - DOI : 10.1016 / 0022-5088 (83) 90230-8 .
  3. ↑ 1 2 B. Predel. Cu-Nd (Copper-Neodymium) // Landolt-Börnstein - Group IV Physical Chemistry. - 1994 .-- T. 5d . - S. 1-3 . - DOI : 10.1007 / 10086090_1094 .
  4. ↑ Shigeru Takayanagi, Nobuo Wada, Yoshichika Ōnuki, Takemi Komatsubara. Magnetic Phase Diagram in the Canting Antiferromagnet NdCu 6 // Journal of the Physical Society of Japan. - 1991 .-- T. 60 . - S. 975-981 . - DOI : 10.1143 / JPSJ.60.975 .



Source - https://ru.wikipedia.org/w/index.php?title=Hexamedneodymium&oldid=80937446


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