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Trisodium Antimonide

Trisodium antimonide - a binary inorganic compound of sodium and antimony with the formula Na 3 Sb, dark blue crystals, reacts with water.

Trisodium Antimonide
Are common
Systematic
name
Trisodium Antimonide
Traditional namesAntimony Sodium
Chem. formulaNa 3 Sb
Physical properties
conditiondark blue crystals
Molar mass190.73 g / mol
Density2.6 g / cm³
Thermal properties
T. melt.856 ° C
Like heat resistant.128 J / (molK)
Enthalpy of Education-227 kJ / mol
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • Inert atmosphere fusion (Ar) of stoichiometric amounts of pure substances:
3Na+Sb→900oCNa3Sb{\ displaystyle {\ mathsf {3Na + Sb \ {\ xrightarrow {900 ^ {o} C}} \ Na_ {3} Sb}}}  

Physical Properties

Trisodium antimonide forms dark blue crystals of hexagonal syngony , space group P 6 3 / mmc , cell parameters a = 0.5355 nm, c = 0.9496 nm, Z = 2.

At high pressures (3 GPa), a transition to the cubic syngony phase occurs, the cell parameters a = 0.740 nm.

Application

  • How photoemission material is used as photocathodes .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.
  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .



Source - https://ru.wikipedia.org/w/index.php?title=Trimatium antimonide&oldid = 80360202


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Clever Geek | 2019