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Sodium trihydroorthoperiodate

Sodium trihydroorthoperiodate is an inorganic compound, an acid salt of sodium and orthiodic acid with the formula Na 2 H 3 IO 6 , colorless crystals, slightly soluble in water.

Sodium trihydroorthoperiodate
Are common
Systematic
name
Sodium trihydroorthoperiodate
Traditional namesSodium Sodium Acid
Chem. formulaNa 2 H 3 IO 6
Physical properties
conditioncolorless crystals
Molar mass271.90 g / mol
Density3.6 g / cm³
Thermal properties
T. decomp.200 ° C
Chemical properties
Solubility in water0.15 25 ; 0.43 100 g / 100 ml
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi

Content

Getting

  • Passing chlorine through a boiling alkaline solution of sodium iodate
NaIO3+Cl2+3NaOH→100oCNa2H3IO6↓+2NaCl{\ displaystyle {\ mathsf {NaIO_ {3} + Cl_ {2} + 3NaOH \ {\ xrightarrow {100 ^ {o} C}} \ Na_ {2} H_ {3} IO_ {6} \ downarrow + 2NaCl}} }  

Physical Properties

Sodium trihydroorthoperiodate forms colorless crystals of rhombic syngony , space group Pnnm , cell parameters a = 0.4697 nm , b = 0.5299 nm , c = 1.0052 nm , Z = 2 [1] .

Slightly soluble in water.

See also

  • Sodium dihydroorthoperiodate

Notes

  1. ↑ Martin Jansen, Anette Rehr ,. Na 2 H 3 IO 6 , eine Variante der Markasitstruktur // Zeitschrift für anorganische und allgemeine Chemie. - 1988. - T. 567 , No. 1 . - S. 95-100 . - DOI : 10.1002 / zaac.19885670111 .

Literature

  • Handbook of a chemist / Editorial: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ksenzenko V.I., Stasinevich D.S. Chemistry and technology of bromine, iodine and their compounds. - M .: Chemistry, 1995 .-- 432 p. - ISBN 5-7245-0845-1 .


Source - https://ru.wikipedia.org/w/index.php?title= Sodium trihydroorthoperiodate&oldid = 95788253


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