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Tricarbonyl (pyrrolyl) manganese

Tricarbonyl (pyrrolyl) manganese is an organometallic compound , a manganese carbonyl complex of the composition Mn (C 4 H 4 N) (CO) 3 , dark yellow crystals, dissolves in organic solvents.

Tricarbonyl
Are common
Systematic
name
Tricarbonyl (pyrrolyl) manganese
Traditional namesAzacimanthrene
Chem. formulaMn (C 4 H 4 N) (CO) 3
Physical properties
conditiondark yellow crystals
Molar mass205.05 g / mol
Thermal properties
T. melt.41 ° C
T. sub.in vacuum - 35-38 ° C
Classification
ChemSpider

Getting

  • The reaction of decacarbonyldimarganese and pyrrole in octane :
Mn2(CO)ten+2CfourHfiveN→125oC2Mn(CfourHfour N ) ( C O ) 3 + H 2 + four C O{\ displaystyle {\ mathsf {Mn_ {2} (CO) _ {10} + 2C_ {4} H_ {5} N \ {\ xrightarrow {125 ^ {o} C}} \ 2Mn (C_ {4} H_ { 4} N) (CO) _ {3} + H_ {2} + 4CO}}}  

Physical Properties

Tricarbonyl (pyrrolyl) manganese forms dark yellow crystals, stable in air, not very resistant to light.

It is soluble in most organic solvents.

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - Moscow : Mir, 1985 .-- V. 5 .-- 360 p.


Source - https://ru.wikipedia.org/w/index.php?title= Tricarbonyl ( pyrrolyl) manganese&oldid = 95292383


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