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Manganese Tetraborate

Manganese tetraborate is an inorganic compound, a salt of manganese and tetraboric acid with the formula MnB 4 O 7 , crystals, does not dissolve in water, forms crystalline hydrates - pink crystals.

Manganese Tetraborate
General
Systematic
name
Manganese Tetraborate
Traditional namesManganese boric acid, tetra
Chem. formulaMnB 4 O 7
Physical properties
conditionhydrate - pink crystals
Molar mass210.18 g / mol
Density2.8 g / cm³
Classification
Reg. CAS number12228-91-0
PubChem
Reg. EINECS number235-446-7
Smiles
Inchi
ChemSpider

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 Application
  • 4 notes
  • 5 Literature

Getting

  • The interaction of manganese hydroxide and boric acid:
Mn(OH)2+fourH3BO3→MnBfourO7+7H2O{\ displaystyle {\ mathsf {Mn (OH) _ {2} + 4H_ {3} BO_ {3} \ {\ xrightarrow {}} \ MnB_ {4} O_ {7} + 7H_ {2} O}}}  

Physical Properties

Manganese tetraborate forms rhombic syngony crystals, space group P bca , cell parameters a = 0.862354 nm, b = 1.40071 nm, c = 0.807237 nm, Z = 8 [1] .

Not soluble in water and ethanol .

Forms crystalline hydrates of the composition MnB 4 O 7 • n H 2 O, where n = 8 and 9.

Paramagnet at room temperature, antiferromagnet at 3 K.

Application

  • Desiccant .
  • Pigment in oil paints.

Notes

  1. ↑ Abrahams SC, Bernstein JL, Gibart P., Robbins M., Sherwood RC ,. Manganese diborate: Crystal structure, magnetization, and thermal extinction dependence // Journal of Chemical Physics. - 1974. - T. 60 , No. 5 . - S. 1899-1905 . - DOI : 10.1063 / 1.1681292 .

Literature

  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  • Chemical Encyclopedic Dictionary / Editorial: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1983. - 792 p.


Source - https://ru.wikipedia.org/w/index.php?title=Manganese tetraborate&oldid = 80370679


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