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Lutetium fluoride

Lutetium fluoride is an inorganic compound, a salt of lutetium and hydrofluoric acid with the formula LuF 3 , colorless crystals, does not dissolve in water, forms crystalline hydrates .

Lutetium fluoride
Are common
Systematic
name
Lutetium fluoride
Traditional namesLutetium fluoride
Chem. formulaLuF 3
Physical properties
conditioncolorless crystals
Molar mass231.96 g / mol
Density8.29; 8.3 g / cm³
Thermal properties
T. melt.1182; 1184 ° C
T. bale.2200; 2230 ° C
Like heat resistant.87.9 J / (mol · K)
Enthalpy of Education-1673.6 kJ / mol
Classification
Reg. CAS number13760-81-1
PubChem
Reg. EINECS number237-355-8
Smiles
Inchi
ChemSpider

Getting

  • The effect of hydrofluoric acid on soluble salts of lutetium:
L u C l 3 + 3 H F → four L u F 3 ↓ + 3 H C l{\ displaystyle {\ mathsf {LuCl_ {3} + 3HF \ {\ xrightarrow {}} \ 4LuF_ {3} \ downarrow + 3HCl}}} {\displaystyle {\mathsf {LuCl_{3}+3HF\ {\xrightarrow {}}\ 4LuF_{3}\downarrow +3HCl}}}
  • The effect of gaseous hydrogen fluoride on lutetium oxide :
Lu2O3+6HF→2LuF3+3H2O{\ displaystyle {\ mathsf {Lu_ {2} O_ {3} + 6HF \ {\ xrightarrow {}} \ 2LuF_ {3} + 3H_ {2} O}}} {\displaystyle {\mathsf {Lu_{2}O_{3}+6HF\ {\xrightarrow {}}\ 2LuF_{3}+3H_{2}O}}}

Physical Properties

Lutetium fluoride forms colorless crystals of rhombic syngony , space group P nma , cell parameters a = 0.6145 nm, b = 0.6761 nm, c = 0.4472 nm, Z = 4.

At 957 ° С, a transition to the phase of trigonal syngony occurs.

Not soluble in water.

Forms crystalline hydrates.

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1990. - T. 2. - 671 p. - ISBN 5-82270-035-5 .
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  • Chemical Encyclopedic Dictionary / Editorial: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1983. - 792 p.



Source - https://ru.wikipedia.org/w/index.php?title= Lutetium fluoride&oldid = 80372441


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