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Lutetium chloride

Lutetium chloride is an inorganic compound, a salt of lutetium hydroxide and hydrochloric acid with the formula LuCl 3 , colorless crystals, it dissolves in water, forms crystalline hydrates .

Lutetium chloride
Are common
Systematic
name
Lutetium chloride
Traditional namesLutetium chloride
Chem. formulaLuCl 3
Physical properties
conditioncolorless crystals
Molar mass281.33 g / mol
Density3.98 g / cm³
Thermal properties
T. melt.890-895; 925 ° C
T. bale.1480 ° C
Classification
Reg. CAS number10099-66-8, hexahydrate - 15230-79-2
PubChem
Reg. EINECS number
Smiles
Inchi
RTECS
ChemSpider

Getting

  • To obtain anhydrous chloride, the reaction of lutetium oxide and carbon tetrachloride is used :
2Lu2O3+3CClfour→500-700oCfourLuCl3+3CO2{\ displaystyle {\ mathsf {2Lu_ {2} O_ {3} + 3CCl_ {4} \ {\ xrightarrow {500-700 ^ {o} C}} \ 4LuCl_ {3} + 3CO_ {2}}}}  
  • Crystalline hydrate is obtained by dissolving lutetium oxide in hydrochloric acid:
Lu2O3+6HCl→2LuCl3+3H2O{\ displaystyle {\ mathsf {Lu_ {2} O_ {3} + 6HCl \ {\ xrightarrow {}} \ 2LuCl_ {3} + 3H_ {2} O}}}  
  • The crystal hydrate is dehydrated by gradual heating with ammonium chloride (to prevent hydrolysis ):
LuCl3⋅6H2O+mNHfourCl→400oCLuCl3+mNH3+mHCl+6H2O{\ displaystyle {\ mathsf {LuCl_ {3} \ cdot 6H_ {2} O + mNH_ {4} Cl \ {\ xrightarrow {400 ^ {o} C}} \ LuCl_ {3} + mNH_ {3} + mHCl + 6H_ {2} O}}}  

Physical Properties

Lutetium chloride forms colorless crystals.

It is soluble in water.

Forms crystalline hydrates of the composition LuCl 3 • 6H 2 O.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  • Chemical Encyclopedic Dictionary / Editorial: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1983. - 792 p.



Source - https://ru.wikipedia.org/w/index.php?title= Lutetium Chloride&oldid = 101233068


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