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Lithium selenide

Lithium selenide (Li 2 Se) is a salt of lithium and selenic acid.

Lithium selenide
Are common
Systematic
name
Lithium selenide
Traditional namesSelenium lithium
Chem. formulaLi 2 Se
Physical properties
conditionred brown crystals
Molar mass92.84 g / mol
Density2.83 g / cm³
Thermal properties
Enthalpy of Education-381 kJ / mol
Classification
Reg. CAS number12136-60-6
PubChem
Reg. EINECS number235-230-2
Smiles
Inchi
ChemSpider

Getting

  • The reaction of selenium with lithium dissolved in ammonia:
2Li+Se→-33oCLi2Se{\ displaystyle {\ mathsf {2Li + Se \ {\ xrightarrow {-33 ^ {o} C}} \ Li_ {2} Se}}} {\displaystyle {\mathsf {2Li+Se\ {\xrightarrow {-33^{o}C}}\ Li_{2}Se}}}
the resulting white amorphous mass is annealed in vacuum at 150 ° C.

Physical Properties

Lithium selenide forms red-brown hygroscopic crystals of cubic syngony , space group F m 3 m , cell parameters a = 0.6017 nm, Z = 4.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • State Diagrams of Double Metal Systems / Ed. N.P. Lyakisheva. - M .: Engineering, 2001. - T. 3 Book 1. - 972 p. - ISBN 5-217-02843-2 .
  • Plyushchev V.E., Stepin B.D. Chemistry and technology of compounds of lithium, rubidium and cesium. - M .: "Chemistry", 1970. - 408 p.


Source - https://ru.wikipedia.org/w/index.php?title= Lithium selenide&oldid = 80369794


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Clever Geek | 2019