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Lanthanum Selenate (III)

Lanthanum (III) selenate is an inorganic compound, a metal salt of lanthanum and selenic acid with the formula La 2 (SeO 4 ) 3 , colorless crystals, soluble in water, form crystalline hydrates .

Lanthanum Selenate
Are common
Systematic
name
Lanthanum Selenate (III)
Traditional namesLanthanum selenate
Chem. formulaLa 2 (SeO 4 ) 3
Physical properties
conditioncolorless crystals
Molar mass706.68 g / mol
Chemical properties
Solubility in water50.5 0 ; 45 20 ; 2.2 90 g / 100 ml
Classification
ChemSpider

Getting

  • Dissolution of lanthanum oxide , hydroxide or carbonate in selenium acid solution:
La2O3+3H2SeOfour→La2(SeOfour)3+3H2O{\ displaystyle {\ mathsf {La_ {2} O_ {3} + 3H_ {2} SeO_ {4} \ {\ xrightarrow {}} \ La_ {2} (SeO_ {4}) _ {3} + 3H_ {2 } O}}}  
2La(OH)3+3H2SeOfour→La2(SeOfour)3+6H2O{\ displaystyle {\ mathsf {2La (OH) _ {3} + 3H_ {2} SeO_ {4} \ {\ xrightarrow {}} \ La_ {2} (SeO_ {4}) _ {3} + 6H_ {2 } O}}}  
La2(CO3)3+3H2SeOfour→La2(SeOfour)3+3CO2↑+3H2O{\ displaystyle {\ mathsf {La_ {2} (CO_ {3}) _ {3} + 3H_ {2} SeO_ {4} \ {\ xrightarrow {}} \ La_ {2} (SeO_ {4}) _ { 3} + 3CO_ {2} \ uparrow + 3H_ {2} O}}}  

Physical Properties

Lanthanum (III) selenate forms colorless (white) crystals.

It is well dissolved in cold water.

It forms crystalline hydrates of the composition La 2 (SeO 4 ) 3 • n H 2 O, where n = 5, 6, 10 and 12. The most stable is La 2 (SeO 4 ) 3 • 5H 2 O.

Crystalline hydrate of the composition La 2 (SeO 4 ) 3 • 12H 2 O — monoclinic syngony crystals, space group C 2 / c , cell parameters a = 1.0670 nm, b = 2.0390 nm, c = 1.0740 nm, β = 110.12 °.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.


Source - https://ru.wikipedia.org/w/index.php?title= Selenate_lantana ( III)&oldid = 80369671


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