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Bromdisilan

Bromodisilane is an inorganic compound, a bromine derivative of disilane with the formula Si 2 H 5 Br, a colorless liquid, self-igniting in air.

Bromdisilan
Are common
Systematic
name
Bromdisilan
Traditional namesSilicon Pentahydride Bromide; monobromodisilane; disilanyl bromide
Chem. formulaSi 2 H 5 Br
Physical properties
conditioncolorless liquid
Molar mass141.11 g / mol
Thermal properties
T. melt.-97.2 ° C
T. bale.69.5 ° C
T. decomp.> 50 ° C
Classification
ChemSpider

Getting

  • The reaction of disilane and hydrogen bromide :
Si2H6+HBr→AlBr3Si2HfiveBr+H2{\ displaystyle {\ mathsf {Si_ {2} H_ {6} + HBr \ {\ xrightarrow {AlBr_ {3}}} \ Si_ {2} H_ {5} Br + H_ {2}}}} {\displaystyle {\mathsf {Si_{2}H_{6}+HBr\ {\xrightarrow {AlBr_{3}}}\ Si_{2}H_{5}Br+H_{2}}}}
  • Passing iodosilane vapor over silver bromide :
Si2HfiveI+AgBr→Si2HfiveBr+AgI{\ displaystyle {\ mathsf {Si_ {2} H_ {5} I + AgBr \ {\ xrightarrow {}} \ Si_ {2} H_ {5} Br + AgI}}} {\displaystyle {\mathsf {Si_{2}H_{5}I+AgBr\ {\xrightarrow {}}\ Si_{2}H_{5}Br+AgI}}}

Physical Properties

Bromodisilane forms a colorless liquid, self-igniting in air.

It decomposes slowly at room temperature, and quickly at 0 ° C in the presence of traces of aluminum bromide .

Literature

  • Jolly W. Syntheses of inorganic compounds. - M .: Mir, 1966. - T. 1. - 280 p.


Source - https://ru.wikipedia.org/w/index.php?title=Bromdisilan&oldid=80560518


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Clever Geek | 2019