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Bis (trimethylsilyl) sulfane

Bis (trimethylsilyl) sulfane is a chemical compound with the formula [(CH 3 ) 3 Si] 2 S, a colorless, easily hydrolyzed liquid with a sickening odor, toxic.

Bis
Bis (trimethylsilyl) sulfide.png
Are common
Systematic
name
Bis (trimethylsilyl) sulfane
Traditional namesBis (trimethylsilyl) sulfide, hexamethyldisylthian
Chem. formula[(CH 3 ) 3 Si] 2 S
Physical properties
conditioncolorless liquid
Molar mass178.44 g / mol
Density0.851 g / cm³
Thermal properties
T. bale.162 ° C
Optical properties
Refractive index1.4590
Classification
Reg. CAS number3385-94-2
PubChem
Reg. EINECS number222-201-4
Smiles
Inchi
UN number
ChemSpider

Getting

  • The reaction of trimethylchlorosilane and hydrogen sulfide in pyridine :
2(CH3)3SiCl+H2S+2CfiveHfiveN→[(CH3)3Si]2S+CfiveHfiveN⋅HCl{\ displaystyle {\ mathsf {2 (CH_ {3}) _ {3} SiCl + H_ {2} S + 2C_ {5} H_ {5} N \ {\ xrightarrow {}} \ [(CH_ {3}) _ {3} Si] _ {2} S + C_ {5} H_ {5} N \ cdot HCl}}}  

Physical Properties

Bis (trimethylsilyl) sulfane forms a colorless liquid with an unpleasant odor, is easily hydrolyzed .

It is soluble in inert organic solvents.

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.


Source - https://ru.wikipedia.org/w/index.php?title=Bis(trimethylsilyl)sulfan&oldid=80560377


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Clever Geek | 2019