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Dimethylsilyldiisocyanate

Dimethylsilyldiisocyanate is a chemical compound, an alkyl and isocyanide derivative of monosilane with the formula (CH 3 ) 2 Si (NCO) 2 , a colorless liquid with a strong odor.

Dimethylsilyldiisocyanate
Are common
Systematic
name
Dimethylsilyldiisocyanate
Traditional namesDimethyl diisocyanatesilane
Chem. formula(CH 3 ) 2 Si (NCO) 2
Physical properties
conditioncolorless liquid
Molar mass142.19 g / mol
Density0.976 g / cm³
Thermal properties
T. melt.-31 ° C
T. Kip.139; 139.2 ° C
Optical properties
Refractive index1.4226
Classification
Reg. CAS number
Pubchem
Reg. EINECS number
SMILES
Inchi
Chemspider

Getting

  • The reaction of dimethyldichlorosilane and silver cyanate in benzene :
(CH3)2SiCl2+2AgNCO→40oC(CH3)2Si(NCO)2+2AgCl{\ displaystyle {\ mathsf {(CH_ {3}) _ {2} SiCl_ {2} + 2AgNCO \ {\ xrightarrow {40 ^ {o} C}} \ (CH_ {3}) _ {2} Si (NCO ) _ {2} + 2AgCl}}}  

Physical Properties

Dimethylsilyldiisocyanate forms a colorless liquid with a strong odor.

Hydrolyzed in water and moist air.

It is dissolved in inert organic solvents.


Literature

  • Manual on inorganic synthesis: B 6 tons / Ed. Brower G. .. - M .: Mir, 1985. - T. 3. - 392 p.
  • Adrianov K.A. Silicone compounds. - M .: State Scientific and Technical Publishing House of Chemical Literature, 1955. - 521 p.


Source - https://ru.wikipedia.org/w/index.php?title=Dimethylsilyldiisocyanate&oldid=80560238


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