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Silicon tetraisothiocyanate

Silicon tetraisothiocyanate is an inorganic compound, a salt of silicon and thiocyanate with the formula Si (NCS) 4 , colorless crystals, hydrolyzed by water.

Silicon tetraisothiocyanate
General
Systematic
name
Silicon tetraisothiocyanate
Traditional namesSilicon thiocyanate
Chem. formulaSi (NCS) 4
Physical properties
conditioncolorless crystals
Molar mass260.42 g / mol
Thermal properties
T. melt.143.8 ° C
T. bale.313 ° C
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • The reaction of silicon (IV) chloride and ammonium thiocyanate in benzene :
SiClfour+fourNHfourSCN→Si(CNS)four+fourNHfourCl{\ displaystyle {\ mathsf {SiCl_ {4} + 4NH_ {4} SCN \ {\ xrightarrow {}} \ Si (CNS) _ {4} + 4NH_ {4} Cl}}}  

Physical Properties

Silicon tetraisothiocyanate forms colorless, easily hydrolyzed crystals.

It is soluble in chloroform , carbon tetrachloride , acetone , benzene .

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.
  • Jolly W. Syntheses of inorganic compounds. - M .: Mir, 1966. - T. 1. - 280 p.


Source - https://ru.wikipedia.org/w/index.php?title= Silicon tetraisothiocyanate&oldid = 80432109


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Clever Geek | 2019