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Dichlorosilane

Dichlorosilane is an inorganic compound, a chlorine derivative of monosilane with the formula SiH 2 Cl 2 , a colorless gas, self-igniting in air.

Dichlorosilane
Dichlorosilane-2d-stereo.png
Are common
Systematic
name
Dichlorosilane
Traditional namesSilicon dihydride; dichlorosilane
Chem. formulaSiH 2 Cl 2
Physical properties
conditioncolorless gas
Molar mass101.01 g / mol
Density4.129 g / l
Thermal properties
T. melt.-122 ° C
T. bale.8.3 ° C
Enthalpy of Education−320 kJ / mol
Classification
Reg. CAS number4109-96-0
PubChem
Reg. EINECS number
Smiles
Inchi
RTECS
UN number
ChemSpider

Content

Getting

  • The reaction of hydrogen chloride and monosilane in the presence of a catalyst:
SiHfour+HCl→AlCl3,100oCSiH3Cl+H2{\ displaystyle {\ mathsf {SiH_ {4} + HCl \ {\ xrightarrow {AlCl_ {3}, 100 ^ {o} C}} \ SiH_ {3} Cl + H_ {2}}}}  
SiHfour+2HCl→AlCl3,100oCSiH2Cl2+2H2{\ displaystyle {\ mathsf {SiH_ {4} + 2HCl \ {\ xrightarrow {AlCl_ {3}, 100 ^ {o} C}} \ SiH_ {2} Cl_ {2} + 2H_ {2}}}}  
SiHfour+3HCl→AlCl3,100oCSiHCl3+3H2{\ displaystyle {\ mathsf {SiH_ {4} + 3HCl \ {\ xrightarrow {AlCl_ {3}, 100 ^ {o} C}} \ SiHCl_ {3} + 3H_ {2}}}}  
SiHfour+fourHCl→AlCl3,100oCSiClfour+fourH2{\ displaystyle {\ mathsf {SiH_ {4} + 4HCl \ {\ xrightarrow {AlCl_ {3}, 100 ^ {o} C}} \ SiCl_ {4} + 4H_ {2}}}}  
the reaction products are separated by fractional distillation .

Physical Properties

Dichlorosilane forms a colorless gas, self-igniting in air.

Chemical Properties

  • Reacts with water to form a mixture of polysiloxanes.

Literature

  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.
  • Adrianov K.A. Organosilicon compounds. - M .: State Scientific and Technical Publishing House of Chemical Literature, 1955. - 521 p.
  • Jolly W. Syntheses of inorganic compounds. - M .: Mir, 1966. - T. 1. - 280 p.


Source - https://ru.wikipedia.org/w/index.php?title=Dichlorosilane&oldid=80559448


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Clever Geek | 2019