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Disilan

Disilan is a binary inorganic compound of silicon and hydrogen with the formula Si 2 H 6 , a colorless gas with an unpleasant odor, self-igniting in air, reacting with water, and poisonous.

Disilan
Are common
Systematic
name
Disilan
Traditional namesHydrogen hydrogen; silicon hydride
Chem. formulaSi 2 H 6
Physical properties
conditioncolorless gas
Molar mass62.22 g / mol
Density2.543 g / l; 2.85 g / l; 0.686 -25 g / cm³
Thermal properties
T. melt.-132.5; -129.4 ° C
T. bale.-14.8; -14.5 ° C
T. decomp.350-400 ° C
Like heat resistant.79.0 J / (mol · K)
Enthalpy of Education95.76 kJ / mol
Classification
Reg. CAS number1590-87-0
PubChem
Reg. EINECS number
Smiles
Inchi
Chebi
ChemSpider

Getting

  • The reaction of dichromium hexachloride and lithium tetrahydroaluminate :
2Si2Cl6+3LiAlHfour→0oC2Si2H6↑+3LiCl+3AlCl3{\ displaystyle {\ mathsf {2Si_ {2} Cl_ {6} + 3LiAlH_ {4} \ {\ xrightarrow {0 ^ {o} C}} \ 2Si_ {2} H_ {6} \ uparrow + 3LiCl + 3AlCl_ {3 }}}}  

Physical Properties

Disilan forms a colorless gas with an unpleasant odor, spontaneously ignites in air, reacts with water, and dissolves in carbon disulfide , ethanol , and benzene .

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1995. - T. 4. - 639 p. - ISBN 5-82270-092-4 .
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.


Source - https://ru.wikipedia.org/w/index.php?title=Disilan&oldid=98219899


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Clever Geek | 2019