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Chloropentaammine cobalt (III) chloride

Chloropentaammine cobalt (III) chloride ( trivial name - purpureochloride ) is an inorganic compound, a complex amine salt of a cobalt metal and hydrochloric acid with the formula [Co (NH 3 ) 5 Cl] Cl 2 , red crystals, it is slightly soluble in water.

Chloropentaammine cobalt chloride
Are common
Systematic
name
Chloropentaammine cobalt (III) chloride
Traditional namesMonochloropentamine minkobaltichloride, purpureochloride
Chem. formula[Co (NH 3 ) 5 Cl] Cl 2
Physical properties
conditionred crystals
Molar mass250.44 g / mol
Density1,783 g / cm³
Chemical properties
Solubility in water0.22 0 ; 0.56; 1.0 50 ;
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • The reaction of aquapentaammine cobalt (III) oxalate and hydrochloric acid:
[Co(NH3)five(H2O)]2(C2Ofour)3+6HCl→{\ displaystyle {\ mathsf {[Co (NH_ {3}) _ {5} (H_ {2} O)] _ {2} (C_ {2} O_ {4}) _ {3} + 6HCl \ {\ xrightarrow {}} \}}}  
→2[Co(NH3)fiveCl]Cl2↓+3H2C2Ofour+2H2O{\ displaystyle {\ mathsf {\ {\ xrightarrow {}} \ 2 [Co (NH_ {3}) _ {5} Cl] Cl_ {2} \ downarrow + 3H_ {2} C_ {2} O_ {4} + 2H_ {2} O}}}  

Physical Properties

Chloropentaammine cobalt (III) chloride forms red crystals of rhombic syngony , space group P nma , cell parameters a = 1.334 nm, b = 1.033 nm, c = 0.673 nm, Z = 4.

It is slightly soluble in water, not soluble in dilute hydrochloric acid.

Literature

  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - Moscow : Mir, 1985 .-- V. 5 .-- 360 p.


Source - https://ru.wikipedia.org/w/index.php?title= Chloropentaammine cobalt chloride ( III)&oldid = 80382317


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Clever Geek | 2019