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Potassium fluorochromate

Potassium fluorochromate is an inorganic compound, a salt of potassium and fluorochrome acid with the formula KCrO 3 F, red crystals, it dissolves in water with decomposition.

Potassium fluorochromate
Are common
Systematic
name
Potassium fluorochromate
Traditional namesPotassium trioxofluorochromate (VI)
Chem. formulaKCrO 3 F
Physical properties
conditionred crystals
Molar mass158.09 g / mol

Content

Getting

  • The reaction of potassium dichromate with an excess of hot dilute hydrofluoric acid:
K2Cr2O7+2HF→T2KCrO3F+H2O{\ displaystyle {\ mathsf {K_ {2} Cr_ {2} O_ {7} + 2HF \ {\ xrightarrow {T}} \ 2KCrO_ {3} F + H_ {2} O}}}  

Physical Properties

Potassium fluorochromate forms red crystals of tetragonal syngony , space group I 4 1 / a , cell parameters a = 0.546 nm, c = 1.289 nm? Z = 4.

Slowly destroys glass.

Chemical Properties

  • It decomposes in hot water:
2KCrO3F+H2O→TK2Cr2O7+2HF{\ displaystyle {\ mathsf {2KCrO_ {3} F + H_ {2} O \ {\ xrightarrow {T}} \ K_ {2} Cr_ {2} O_ {7} + 2HF}}}  

Literature

  • Ryss I.G. Chemistry of fluorine and its inorganic compounds. - 1956. - 722 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.


Source - https://ru.wikipedia.org/w/index.php?title= Potassium fluorochromat&oldid = 80504286


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Clever Geek | 2019