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Potassium thiostanate

Potassium thiostanate - an inorganic compound, thiosol of potassium and tin acid with the formula K 2 SnS 3 , dissolved in water, forms crystalline hydrates .

Potassium thiostanate
Are common
Systematic
name
Potassium thiostanate
Traditional namesPotassium Dioxide
Chem. formulaK 2 SnS 3
Physical properties
Molar mass293.10 g / mol
Densitytrihydrate - 1,847 g / cm³

Getting

  • Dissolution of tin disulfide in potassium hydroxide solution:
3SnS2+6KOH→2K2SnS3+K2SnO3+3H2O{\ displaystyle {\ mathsf {3SnS_ {2} + 6KOH \ {\ xrightarrow {}} \ 2K_ {2} SnS_ {3} + K_ {2} SnO_ {3} + 3H_ {2} O}}}  

Physical Properties

Potassium thiostanate forms crystalline hydrates of the composition K 2 SnS 3 • n H 2 O, where n = 2 and 3.

Soluble in water, not soluble in ethanol .

K 2 SnS 3 • 3H 2 O crystalline hydrate is a dark brown liquid.

K 2 SnS 3 • 2H 2 O crystalline forms rhombic crystals, space group P nma , cell parameters a = 0.6429 nm, b = 1.5621 nm, c = 1.0569 nm.

Literature

  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Manual on inorganic synthesis: B 6 tons / Ed. Brower G. .. - M .: Mir, 1985. - T. 3. - 392 p.


Source - https://ru.wikipedia.org/w/index.php?title= Tiostanate_kalia&oldid = 80371204


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