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Yttrium Phosphate

Yttrium phosphate is an inorganic compound, a salt of yttrium and phosphoric acid with the formula YPO 4 , colorless crystals, forms crystalline hydrates .

Yttrium Phosphate
Are common
Systematic
name
Yttrium Phosphate
Traditional namesYttrium Phosphate; yttrium orthophosphate
Chem. formulaYPO 4
Physical properties
conditioncolorless crystals
Molar mass183.88 g / mol
Density4.277 g / cm³
Classification
Reg. CAS number13990-54-0, 34054-55-2
PubChem
Reg. EINECS number
Smiles
Inchi
Reg. EC number237-790-3
ChemSpider

Content

Getting

  • In nature, there is a relatively rare mineral xenotime - YPO 4 with impurities of dysprosium , erbium , terbium and ytterbium ; impurities of thorium and uranium are common (all replace yttrium). Due to the impurities of uranium and thorium, some xenotime samples may be weakly or strongly radioactive [1] .
  • The reaction of yttrium chloride and phosphoric acid, followed by the addition of ammonia solution:
YCl3+H3POfour+3NH3⋅H2O→35-40oCYPOfour+3NHfourCl+3H2O{\ displaystyle {\ mathsf {YCl_ {3} + H_ {3} PO_ {4} + 3NH_ {3} \ cdot H_ {2} O \ {\ xrightarrow {35-40 ^ {o} C}} \ YPO_ { 4} + 3NH_ {4} Cl + 3H_ {2} O}}}  

Physical Properties

Yttrium phosphate forms colorless crystals of tetragonal syngony, cell parameters a = 0.68832 nm, c = 0.60208 nm.

Forms crystalline hydrates of the composition YPO 4 • n H 2 O, where n = 1 and 2.

Crystalline hydrate of the composition YPO 4 • 2H 2 O — colorless crystals of monoclinic syngony , space group B 2 / b , cell parameters a = 0.648 nm, b = 1.512 nm, c = 0.628 nm, β = 129.4 °, Z = 4.


Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower G. - M .: Mir, 1985 .-- T. 4 .-- 447 p.

Notes

  1. ↑ Material from GeoWiki, an open encyclopedia on earth sciences. Xenotime- (Y).


Source - https://ru.wikipedia.org/w/index.php?title= Yttrium phosphate&oldid = 80372253


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Clever Geek | 2019