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Indium Phosphate (III)

Indium (III) phosphate is an inorganic compound, a salt of indium and phosphoric acid with the formula InPO 4 , colorless crystals, does not dissolve in water, forms crystalline hydrates .

Indium phosphate
General
Systematic
name
Indium Phosphate (III)
Traditional namesIndium phosphate; indium orthophosphate
Chem. formulaInpo 4
Physical properties
conditioncolorless crystals
Molar mass209.79 g / mol
Density4.9 g / cm³
Chemical properties
Solubility in waternot soluble
Classification
Reg. CAS number14693-82-4

Getting

  • Exchange reaction with indium (III) chloride :
InCl3+H3POfour→InPOfour↓+3HCl{\ displaystyle {\ mathsf {InCl_ {3} + H_ {3} PO_ {4} \ {\ xrightarrow {}} \ InPO_ {4} \ downarrow + 3HCl}}}  

Physical Properties

Indium (III) phosphate forms colorless crystals.

Not soluble in water.

Forms crystalline hydrates of the composition InPO 4 • n H 2 O, where n = 1 and 2.

The monohydrate crystallizes in triclinic syngony , space group P 1 , cell parameters a = 0.54342 nm, b = 0.55508 nm, c = 0.65446 nm, α = 97.593 °, β = 94.558 °, γ = 107.565 °, Z = 2, loses water in the temperature range 370 ÷ 480 ° C.

The dihydrate forms rhombic syngony crystals, space group P bca , cell parameters a = 0.8850 nm, b = 1.0176 nm, c = 1.0313 nm, Z = 8, d c = 3.516 g / cm³.

Literature

  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.



Source - https://ru.wikipedia.org/w/index.php?title= Phosphate_indium ( III)&oldid = 80372252


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