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Tin hexacyanoferrate (II)

Tin hexacyanoferrate (II) is an inorganic compound, a salt of tin and ferruginous acid with the formula Sn 2 [Fe (CN) 6 ], white crystals, insoluble in water.

Hexacyanoferrate
General
Systematic
name
Tin hexacyanoferrate (II)
Traditional namesTin hexacyanoferrate; tin hexacyanoferroate
Chem. formulaSn 2 [Fe (CN) 6 ]
Physical properties
conditionwhite crystals
Molar mass449.37 g / mol
Chemical properties
Solubility in waternot soluble

Getting

  • The reaction of tin chloride and potassium hexacyanoferrate (II) :
2SnCl2+Kfour[Fe(CN)6]→Sn2[Fe(CN)6]↓+fourKCl{\ displaystyle {\ mathsf {2SnCl_ {2} + K_ {4} [Fe (CN) _ {6}] \ {\ xrightarrow {}} \ Sn_ {2} [Fe (CN) _ {6}] \ downarrow + 4KCl}}}  

Physical Properties

Tin hexacyanoferrate (II) forms white crystals.

Not soluble in water.

It forms a crystalline hydrate of variable composition Sn 2 [Fe (CN) 6 ] • x H 2 O, which, when dried in air, acquires a bluish color due to partial decomposition.


Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Tanaev I.V. Chemistry of ferrocyanides. - M .: Nauka, 1971. - 320 p.
Source - https://ru.wikipedia.org/w/index.php?title=Hexacyanoferrat(II)_tin&oldid=80361969


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