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Europium silicide

Europium silicide - a binary inorganic compound of europium and silicon with the formula EuSi 2 , tetragonal crystals.

Europium silicide
Are common
Systematic
name
Europium silicide
Traditional namesSiliceous europium
Chem. formulaEuSi 2
Physical properties
conditiontetragonal crystals
Molar mass208.14 g / mol
Density5.46 g / cm³
Thermal properties
T. melt.1500 ° C
Classification
Reg. CAS number12434-24-1
Reg. EINECS number

Content

Getting

  • Sintering of pure substances in an inert atmosphere:
Eu+2Si→1450oCEuSi2{\ displaystyle {\ mathsf {Eu + 2Si \ {\ xrightarrow {1450 ^ {o} C}} \ EuSi_ {2}}}}  
  • Recovery of europium (III) oxide with silicon in vacuum :
Eu2O3+7Si→1100-1600oC2EuSi2+3SiO{\ displaystyle {\ mathsf {Eu_ {2} O_ {3} + 7Si \ {\ xrightarrow {1100-1600 ^ {o} C}} \ 2EuSi_ {2} + 3SiO}}}  

Physical Properties

Europium silicide forms tetragonal crystal crystals, cell parameters a = 0.429 nm , c = 1.366 nm .


Application

Europium silicide in the form of thin films is used in integrated microelectronics.

Literature

  • CRC Handbook of Chemistry and Physics . - 89th edition. - Taylor and Francis Group, LLC, 2008–2009.
  • Nekrasov B.V. Basics of General Chemistry. - 3rd ed., Corr. and additional .. - M .: "Chemistry", 1973. - T. 2. - 688 p.
  • Samsonov G.V. Chemistry of silicates of rare-earth elements // Successes of Chemistry. - 1962. - Vol . 21 , No. 12 . - p . 1478-1495 .


Source - https://ru.wikipedia.org/w/index.php?title=Silicide_Europe&oldid=80369992


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